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Electrochemical, Spectroscopic and Computational Studies on Complexation of Oxacillin with Cu(II) and Co(II) ions. Synthesis and Ligand Hydrolysis

dc.contributor.authorCoskun, Emine
dc.contributor.authorDuman, Emel
dc.contributor.authorAcar, Nursel
dc.contributor.authorBicer, Ender
dc.date.accessioned2020-06-21T13:18:06Z
dc.date.available2020-06-21T13:18:06Z
dc.date.issued2017
dc.identifier.issn1452-3981
dc.identifier.urihttps://doi.org/10.20964/2017.10.43
dc.identifier.urihttps://hdl.handle.net/20.500.12712/12198
dc.descriptionSelcuki, Nursel Acar/0000-0001-9292-0637en_US
dc.descriptionWOS: 000414422900044en_US
dc.description.abstractIn this study, the synthesis and characterization of the complexes of oxacillin with Cu(II) and Co(II) ions are presented. These complexes were characterized by FT-IR spectroscopy and elemental analysis. The complexation process of Cu(II) and Co(II) ions with oxacillin in aqueous medium (Britton-Robinson buffer pH 7.4) was followed by means of square-wave voltammetry. Spectroscopic and elemental analysis results showed that Co(II) and Cu(II) complexes were formed with hydrolysed oxacillin anions. In addition, their stability constants and stoichiometric ratios were determined from voltammetric data. Computational results are in agreement with the experimental findings.en_US
dc.description.sponsorshipOndokuz Mayis University Research FundOndokuz Mayis University [PYO.FEN. 1904.13.007]en_US
dc.description.sponsorshipThis study was supported by Ondokuz Mayis University Research Fund through project number PYO.FEN. 1904.13.007. The authors are thankful to English Lecturer Mustafa Coskun (Ondokuz Mayis University, Samsun-Turkey) for valuable contributions. Also, we acknowledge the support of Ege University, Faculty of Science HPC resources (FenCluster) for most of the calculations.en_US
dc.language.isoengen_US
dc.publisherEsgen_US
dc.relation.isversionof10.20964/2017.10.43en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectHydrolysisen_US
dc.subjectoxacillin - metal ion complexesen_US
dc.subjectsquare-wave voltammetryen_US
dc.subjectinfrared spectroscopyen_US
dc.subjectdensity functional theoryen_US
dc.titleElectrochemical, Spectroscopic and Computational Studies on Complexation of Oxacillin with Cu(II) and Co(II) ions. Synthesis and Ligand Hydrolysisen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume12en_US
dc.identifier.issue10en_US
dc.identifier.startpage9364en_US
dc.identifier.endpage9377en_US
dc.relation.journalInternational Journal of Electrochemical Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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