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dc.contributor.authorTascioglu, Sulin
dc.contributor.authorAydin, Adnan
dc.contributor.authorYalcin, Bahattin
dc.contributor.authorKaki, Esra
dc.contributor.authorAndac, Omer
dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.authorKosar, Basak
dc.date.accessioned2020-06-21T14:39:44Z
dc.date.available2020-06-21T14:39:44Z
dc.date.issued2011
dc.identifier.issn0277-5387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2011.05.018
dc.identifier.urihttps://hdl.handle.net/20.500.12712/17073
dc.descriptionAndac, Omer/0000-0003-3641-9690; Yalcin, Bahattin/0000-0003-4448-1101en_US
dc.descriptionWOS: 000294572900001en_US
dc.description.abstractFour copper(II) coordination polymers, {[Cu(pz(COO)(2))(H2O)](4)center dot HBr}(n) (1). {[Cu(pz(COO)(2))(NH3)(2)]center dot H2O}(n) (2), {[Cu3H2(pz(COO)(2))(4)(H2O)(3)]center dot 2H(2)O}(n) (3) and {[Cu-2(pz(COO)(2))(2)(NH3)(2)(H2O)(3)][Cu(pz(COO)(2))(NH3) (H2O)(2)][Cu(pz(COO)(2))(NH3)(H2O)]center dot 2H(2)O}(n) (4) were synthesized using pyrazine-2,3-dicarboxylic acid, CuBr2, 2-(2-aminoethylamino)ethanol/triethanol amine/ammonia in a methanol:water (1:1) solution, and the mixed ligand complexes were characterized by spectroscopic methods, thermal and elemental analysis, and magnetic susceptibility. Complexes 2 and 4 were also characterized by means of single crystal X-ray crystallography. The characterizations show that the complexes have polynuclear molecular structures, except for complex 2, and all of the complex structures form polymeric chains. Complex 4 has a pseudo-merohedral twin structure. (C) 2011 Elsevier Ltd. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.isversionof10.1016/j.poly.2011.05.018en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPyrazine-2,3-dicarboxylic aciden_US
dc.subjectCopper(II) bromide complexesen_US
dc.subjectCopper(II) mixed ligand complexesen_US
dc.subjectTwin structureen_US
dc.titleSynthesis and characterization of Cu(II) complexes of pyrazine-2,3-dicarboxylicaciden_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume30en_US
dc.identifier.issue13en_US
dc.identifier.startpage2171en_US
dc.identifier.endpage2180en_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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