dc.contributor.author | Tascioglu, Sulin | |
dc.contributor.author | Aydin, Adnan | |
dc.contributor.author | Yalcin, Bahattin | |
dc.contributor.author | Kaki, Esra | |
dc.contributor.author | Andac, Omer | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.contributor.author | Kosar, Basak | |
dc.date.accessioned | 2020-06-21T14:39:44Z | |
dc.date.available | 2020-06-21T14:39:44Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://doi.org/10.1016/j.poly.2011.05.018 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/17073 | |
dc.description | Andac, Omer/0000-0003-3641-9690; Yalcin, Bahattin/0000-0003-4448-1101 | en_US |
dc.description | WOS: 000294572900001 | en_US |
dc.description.abstract | Four copper(II) coordination polymers, {[Cu(pz(COO)(2))(H2O)](4)center dot HBr}(n) (1). {[Cu(pz(COO)(2))(NH3)(2)]center dot H2O}(n) (2), {[Cu3H2(pz(COO)(2))(4)(H2O)(3)]center dot 2H(2)O}(n) (3) and {[Cu-2(pz(COO)(2))(2)(NH3)(2)(H2O)(3)][Cu(pz(COO)(2))(NH3) (H2O)(2)][Cu(pz(COO)(2))(NH3)(H2O)]center dot 2H(2)O}(n) (4) were synthesized using pyrazine-2,3-dicarboxylic acid, CuBr2, 2-(2-aminoethylamino)ethanol/triethanol amine/ammonia in a methanol:water (1:1) solution, and the mixed ligand complexes were characterized by spectroscopic methods, thermal and elemental analysis, and magnetic susceptibility. Complexes 2 and 4 were also characterized by means of single crystal X-ray crystallography. The characterizations show that the complexes have polynuclear molecular structures, except for complex 2, and all of the complex structures form polymeric chains. Complex 4 has a pseudo-merohedral twin structure. (C) 2011 Elsevier Ltd. All rights reserved. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.isversionof | 10.1016/j.poly.2011.05.018 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Pyrazine-2,3-dicarboxylic acid | en_US |
dc.subject | Copper(II) bromide complexes | en_US |
dc.subject | Copper(II) mixed ligand complexes | en_US |
dc.subject | Twin structure | en_US |
dc.title | Synthesis and characterization of Cu(II) complexes of pyrazine-2,3-dicarboxylicacid | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 30 | en_US |
dc.identifier.issue | 13 | en_US |
dc.identifier.startpage | 2171 | en_US |
dc.identifier.endpage | 2180 | en_US |
dc.relation.journal | Polyhedron | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |