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The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer

dc.contributor.authorGunay, M. Emin
dc.contributor.authorÖzdemir, Namık
dc.contributor.authorUlusoy, Mahmut
dc.contributor.authorUcak, Melih
dc.contributor.authorDinçer, Muharrem
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2020-06-21T15:06:24Z
dc.date.available2020-06-21T15:06:24Z
dc.date.issued2009
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2009.02.023
dc.identifier.urihttps://hdl.handle.net/20.500.12712/18597
dc.descriptionOzdemir, Namik/0000-0003-3371-9874; ulusoy, mahmut/0000-0002-8232-0555; Cetinkaya, Bekir/0000-0002-4551-8650en_US
dc.descriptionWOS: 000266270500007en_US
dc.description.abstractDeprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium center via NH group to give 5a. The hydrolysis necessitates the study of NHC complex formation in anhydrous media. The new compounds were characterized by spectroscopic methods and three of them (3c, 4c, 5a) by X-ray single-crystal diffraction studies. (C) 2009 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipTUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [104T203]; Adnan Menderes UniversityAdnan Menderes University [FEF-07006, FEF-07013, FBE-08001]; Ondokuz Mayis UniversityOndokuz Mayis University [F-425]en_US
dc.description.sponsorshipFinancial support from TUBITAK ( Project: 104T203), Adnan Menderes University ( Project No: FEF-07006, FEF-07013 and FBE-08001) and Ondokuz Mayis University ( Project: F-425) are gratefully acknowledged.en_US
dc.language.isoengen_US
dc.publisherElsevier Science Saen_US
dc.relation.isversionof10.1016/j.jorganchem.2009.02.023en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladacyclesen_US
dc.subjectImidazolinium saltsen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjectRing openingen_US
dc.subjectHydrolysisen_US
dc.titleThe influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimeren_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume694en_US
dc.identifier.issue14en_US
dc.identifier.startpage2179en_US
dc.identifier.endpage2184en_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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