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A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag center dot center dot center dot C interactions: Synthesis, IR spectra and X-ray structure

dc.contributor.authorYılmaz, Veysel T.
dc.contributor.authorHamamci, Sevim
dc.contributor.authorKazak, Canan
dc.date.accessioned2020-06-21T15:12:43Z
dc.date.available2020-06-21T15:12:43Z
dc.date.issued2008
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2008.09.053
dc.identifier.urihttps://hdl.handle.net/20.500.12712/19073
dc.descriptionKazak, Canan/0000-0003-2475-8775; Yilmaz, Veysel/0000-0002-2849-3332en_US
dc.descriptionWOS: 000261162900014en_US
dc.description.abstractA new dinuclear silver(I)-saccharinato (sac) complex with acetonitrile (MeCN), [Ag-2(sac)(2)(MeCN)(2)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by two sac ligands, leading to a short argentophilic contact of 2.9074(3) angstrom. Each silver(I) ion exhibits a square-planar coordination geometry including the Ag-Ag bonds. The individual dimeric molecules are extended into a two-dimensional layered structure by weak Ag center dot center dot center dot Csac(eta(2)) interactions of ca. 3.2 angstrom. These interactions were discussed and compared with those found in the first silver(I)-sac complex [Ag(sac)](n). (C) 2008 Elsevier B.V. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherElsevier Science Saen_US
dc.relation.isversionof10.1016/j.jorganchem.2008.09.053en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSquare-planar silver(I)en_US
dc.subjectSaccharinateen_US
dc.subjectCoordination polymeren_US
dc.subjectAg center dot center dot center dot Ag interactionen_US
dc.subjectAg center dot center dot center dot C interactionen_US
dc.titleA novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag center dot center dot center dot C interactions: Synthesis, IR spectra and X-ray structureen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume693en_US
dc.identifier.issue26en_US
dc.identifier.startpage3885en_US
dc.identifier.endpage3888en_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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